Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation
نویسندگان
چکیده
منابع مشابه
Coordination-driven self-assembly directs a single-crystal-to-single-crystal transformation that exhibits photocontrolled fluorescence.
Coordination-driven self-assembly is employed to direct a single-crystal-to-single-crystal [2 + 2] photodimerization that exhibits tunable fluorescence.
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The coordination polymer [Zn(2)(1,2-bda)(2)(bpe)]·MeOH, which exhibits solvochromic effects upon reversible linear alcohol removal and adsorption, can be turned into [Zn(2)(1,2-bda)(2)(tpcb)(0.5)] in two-step SCSC transformations.
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Photochemical single-crystal to single-crystal transformation of one 1D polymer [Cd(bpe)(CBA)(2)](n) afforded a new 1D polymer [Cd(rctt-tpcb)(0.5)(CBA)(2)](n) which underwent hydrothermal reaction in strong acidic solution to form a 3D coordination polymer {[Cd(rtct-tpcb)Cl(2)]·2H(2)O}(n).
متن کاملA series of isostructural mesoporous metal-organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation.
A series of metal-organic frameworks representing a non-interpenetrated framework analogue of MOF-14 have been synthesized by using two different linkers, 4,4',4''-benzene-1,3,5-triyl-benzoic acid (H(3)BTB) and 4,4'-bipyridine (Bpy). Interestingly, the transition metal ions in the paddle-wheel metal clusters could be exchanged by other transition metal ions via a direct single-crystal to single...
متن کاملReversible single-crystal to single-crystal polymorphic phase transformation of an organic crystal.
Two polymorphs of a substituted dihydroanthracene derivative were prepared by crystallization from different solvents. Each polymorph is reversibly interconvertible to the other by means of a single-crystal to single-crystal phase transformation.
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2016
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c6cc07653j